PSG were in front after half an hour when Kylian Mbappe converted a penalty to become the youngest player to score 25 goals in the tournament.
Messi, however, levelled for 1-1 with a 25-yard drive which flew past Keylor Navas in goal.
Messi then missed a penalty on the stroke of half-time as he exited the tournament just 24 hours after fellow veteran star Cristiano Ronaldo of Juventus was also knocked out.
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